{"created":"2023-05-15T16:34:09.310233+00:00","id":6656,"links":{},"metadata":{"_buckets":{"deposit":"210bcb95-66e4-4a95-a067-0d0029b1d683"},"_deposit":{"created_by":2,"id":"6656","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"6656"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00006656","sets":["14:21"]},"author_link":["28042","28037","28034","28044","28035","28043","28038","28041","28040","28046","28039","28036","28045"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-07-12","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"2162","bibliographicVolumeNumber":"4","bibliographic_titles":[{"bibliographic_title":"Nature Communications"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Despite extensive research for more than 200 years, the experimental isolation of monatomic sulphur chains, which are believed to exhibit a conducting character, has eluded scientists. Here we report the synthesis of a previously unobserved composite material of elemental sulphur, consisting of monatomic chains stabilized in the constraining volume of a carbon nanotube. This one-dimensional phase is confirmed by high-resolution transmission electron microscopy and synchrotron X-ray diffraction. Interestingly, these one-dimensional sulphur chains exhibit long domain sizes of up to 160 nm and high thermal stability (∼800 K). Synchrotron X-ray diffraction shows a sharp structural transition of the one-dimensional sulphur occurring at ∼450-650 K. Our observations, and corresponding electronic structure and quantum transport calculations, indicate the conducting character of the one-dimensional sulphur chains under ambient pressure. This is in stark contrast to bulk sulphur that needs ultrahigh pressures exceeding ∼90 GPa to become metallic.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Nature Communications, 4, 2162; 2013","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Nature Publishing Group"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1038/ncomms3162","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2013 Macmillan Publishers Limited. All rights reserved."},{"subitem_rights":"This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. To view a copy of this licence visit http:// creativecommons.org/licenses/by/3.0/."}]},"item_2_source_id_8":{"attribute_name":"EISSN","attribute_value_mlt":[{"subitem_source_identifier":"20411723","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Fujimori, Toshihiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Morelos-Gómez, Aarón"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Zhu, Zhen"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Muramatsu, Hiroyuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Futamura, Ryusuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Urita, Koki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Terrones, Mauricio"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hayashi, Takuya"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Endo, Morinobu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Young, Hong  Sang"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Chul, Choi  Young"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tománek, David"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kaneko, Katsumi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"NaCom4_2162.pdf","filesize":[{"value":"2.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"NaCom4_2162.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/6656/files/NaCom4_2162.pdf"},"version_id":"cd693a0d-e4fc-42a7-9024-cae98791b398"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Conducting linear chains of sulphur inside carbon nanotubes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Conducting linear chains of sulphur inside carbon nanotubes"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-09-12"},"publish_date":"2013-09-12","publish_status":"0","recid":"6656","relation_version_is_last":true,"title":["Conducting linear chains of sulphur inside carbon nanotubes"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T02:40:31.850680+00:00"}