{"created":"2023-05-15T16:34:47.174948+00:00","id":7526,"links":{},"metadata":{"_buckets":{"deposit":"cd200928-0d11-462d-993d-adb1f57b59c9"},"_deposit":{"created_by":2,"id":"7526","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"7526"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00007526","sets":["73:74"]},"author_link":["31516","31514","31520","31517","31515","31518","31519"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"429","bibliographicPageStart":"425","bibliographicVolumeNumber":"51","bibliographic_titles":[{"bibliographic_title":"Journal of Chromatographic Science"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Butyl methacrylate (BMA)-ethylene dimethacrylate (EDMA)-methacrylic acid (MAA) and BMA-EDMA-2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) monolithic columns were prepared by varying the percentage of ionic monomers for capillary electrochromatography. Monolithic columns with a higher content of ionic monomers provided better column efficiency, and the performance of BMA-EDMA-MAA monoliths was better than BMA-EDMA-AMPS. To characterize and optimize BMA-EDMA-MAA monoliths, the effects of the content of cross-linker and the total monomer in the polymerization mixture on column performance were also studied. Plate heights of 8.2μm for the unretained solute (thiourea) and 12.6μm for the retained solute (naphthalene) were achieved with a monolithic column using 2.5% MAA (Column I).","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Journal of Chromatographic Science, 51(5), pp.425-429; 2013","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Oxford University Press"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1093/chromsci/bms158","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2012 Published by Oxford University Press. All rights reserved."},{"subitem_rights":"This is a pre-copy-editing, author-produced PDF of an article accepted for publication in Journal of Chromatographic Science following peer review. The definitive publisher-authenticated version Journal of Chromatographic Science, 51 (5), pp. 425-429; 2013 is available online at: http://dx.doi.org/10.1093/chromsci/bms158"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00219665","subitem_source_identifier_type":"ISSN"}]},"item_2_source_id_8":{"attribute_name":"EISSN","attribute_value_mlt":[{"subitem_source_identifier":"1945239X","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Horiguchi, Daisuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ohyama, Kaname"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Masunaga, Tomoko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujita, Yoshiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ali, Marwa Fathy Bakr"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kishikawa, Naoya"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kuroda, Naotaka"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"JCS51_425.pdf","filesize":[{"value":"910.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JCS51_425.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/7526/files/JCS51_425.pdf"},"version_id":"3f19998f-108d-4ff7-864d-388048f41f7c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Capillary electrochromatography","subitem_subject_scheme":"Other"},{"subitem_subject":"Butyl methacrylate-based monolith","subitem_subject_scheme":"Other"},{"subitem_subject":"Methacrylic acid","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Characterization and Comparison of Methacrylic Acid with 2-Acrylamido-2-methyl-1-propanesulfonic Acid in the Preparation of Monolithic Column for Capillary Electrochromatography","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Characterization and Comparison of Methacrylic Acid with 2-Acrylamido-2-methyl-1-propanesulfonic Acid in the Preparation of Monolithic Column for Capillary Electrochromatography"}]},"item_type_id":"2","owner":"2","path":["74"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-06-01"},"publish_date":"2014-06-01","publish_status":"0","recid":"7526","relation_version_is_last":true,"title":["Characterization and Comparison of Methacrylic Acid with 2-Acrylamido-2-methyl-1-propanesulfonic Acid in the Preparation of Monolithic Column for Capillary Electrochromatography"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T02:22:35.252663+00:00"}