{"created":"2023-05-15T16:34:49.088806+00:00","id":7571,"links":{},"metadata":{"_buckets":{"deposit":"208e8a3a-c3de-479e-ae87-5a6e67640e68"},"_deposit":{"created_by":2,"id":"7571","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"7571"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00007571","sets":["18:105:369:551"]},"author_link":["31664","31662","31660","31661","31663"],"item_3_alternative_title_19":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Mechanism of Potential Occurrence of Half-Cell -pH and Potential-"}]},"item_3_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1989-02-28","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"40","bibliographicPageStart":"33","bibliographicVolumeNumber":"40","bibliographic_titles":[{"bibliographic_title":"長崎大学教育学部自然科学研究報告"},{"bibliographic_title":"Science bulletin of the Faculty of Education, Nagasaki University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"It becomes clear that the potentials of a Daniell cell do not occur due to electrons which come from oxidation reaction Zn→Zn2++2e- and reduction one Cu2+2e-→Cu, but due to electrons which come from the following oxidation reaction M (Zn, Cu) +nH+→Mn++n/2・H2+ne-. Therefore a Daniel cell should be expressed by Cu| H+(xm)||H+(xm)|Zn istead of Cu|Cu2+(xm)|Zn. This shows that a voltaic cell Cu|H+(xm)|Zn is same as a Daniell cell Cu|H+(xm)||H+(xm)|Zn, because a salt bridge is only used as circuit of electrons. Accordingly a water cell Cu| H2O| Zn is possible, bebause a water cell is the voltaic cell with solution of 10-7m H+. The equation pH=△E/0.059-1, where △E is the potential of the cell Pt|H|H+(1m)||H+(xm)|H|Pt and pH=-log H+(xm), is theoretically obtained, based upon the above-mentioned mechanism of potential occurrence.","subitem_description_type":"Abstract"}]},"item_3_description_64":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"長崎大学教育学部自然科学研究報告. vol.40, p.33-40; 1989","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"31662","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Hamada, Keinosuke"}]},{"nameIdentifiers":[{"nameIdentifier":"31663","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Rashid, Moktar Bin"}]},{"nameIdentifiers":[{"nameIdentifier":"31664","nameIdentifierScheme":"WEKO"}],"names":[{"name":"浜田, 圭之助"}]}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"長崎大学教育学部"}]},"item_3_relation_29":{"attribute_name":"論文ID（NAID）","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"40002768788","subitem_relation_type_select":"NAID"}}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00178280","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0386443X","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"濱田, 圭之助"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"ラシッド, モクター・ビン"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"kyoikuS40_033.pdf","filesize":[{"value":"551.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"kyoikuS40_033.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/7571/files/kyoikuS40_033.pdf"},"version_id":"52bac751-5a01-4a48-9c2a-a36166d7aa76"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"半電池の起電力発生のメカニズム : pHと起電力","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"半電池の起電力発生のメカニズム : pHと起電力"}]},"item_type_id":"3","owner":"2","path":["551"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-06-25"},"publish_date":"2013-06-25","publish_status":"0","recid":"7571","relation_version_is_last":true,"title":["半電池の起電力発生のメカニズム : pHと起電力"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T02:21:37.316355+00:00"}