{"created":"2023-05-15T16:34:49.130132+00:00","id":7572,"links":{},"metadata":{"_buckets":{"deposit":"e75aac44-2dc4-4093-9771-3d820df17d28"},"_deposit":{"created_by":2,"id":"7572","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"7572"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00007572","sets":["18:105:369:551"]},"author_link":["31673","31674","31668","31669","31666","31672","31670","31667","31671","31665"],"item_3_alternative_title_19":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Vibrational Spectroscopic Study on Trigonal Polyoxymethylene consisting of the Extended Molecular Chains"}]},"item_3_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1989-02-28","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"54","bibliographicPageStart":"41","bibliographicVolumeNumber":"40","bibliographic_titles":[{"bibliographic_title":"長崎大学教育学部自然科学研究報告"},{"bibliographic_title":"Science bulletin of the Faculty of Education, Nagasaki University","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Polarized raman spectra of needle-like and feather-shaped single crystals of trigonal polyoxymethylene (t-POM) consisting of fully extended molecular chains, were measured on a micron-sized cystal by means of the Raman microprobe technique. It was clear that the spectra of these single crystals were quite similar to the spectra of the moth-shaped t-POM single crystals which were obtained by the thermal-induced phase transition of the moth-shaped single crystals of orthorhombic polyoxymethylene1). Polarized Raman spectra of pressurized superdrawn fibers, which were well-oriented and semitransparent samples of t-POM, were obtained theoretically by the ordinary right-angle scattering at room temperature2). In the present study, we could observe the spectraof [YY] polarization of the superdrawn fibers. In addition, twobandsat 1230 and 462 cm-1 in the [YX] polarization, and one band at 198 cm-1 in the[YZ], were newly detected by polarized Raman measurements without the filter for the exitation laser beam, respectivley. And polarized infrared spectra of these fibers were measured, too. The bond assignments of t-POM including the C-H streching vibration reagion were able to be confirmed on the basis of these polarized spectral data. The angular dispersion of E1(7) and E1(8) were measured and discussed on the LO-TO splitting. Raman spectra of needle-like single crystals of polyoxymethylene-d2 consisting of fully extended molecular chains were measured, and it was discussed on the E2 modes.","subitem_description_type":"Abstract"}]},"item_3_description_64":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"長崎大学教育学部自然科学研究報告. vol.40, p.41-54; 1989","subitem_description_type":"Other"}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"31670","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Morishita, Hirofumi"}]},{"nameIdentifiers":[{"nameIdentifier":"31671","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Kobayashi, Masamichi"}]},{"nameIdentifiers":[{"nameIdentifier":"31672","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Shimomura, Masaki"}]},{"nameIdentifiers":[{"nameIdentifier":"31673","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Iguchi, Masatoshi"}]},{"nameIdentifiers":[{"nameIdentifier":"31674","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Kaneko, Fumitoshi"}]}]},"item_3_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"長崎大学教育学部"}]},"item_3_relation_29":{"attribute_name":"論文ID（NAID）","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"40002768785","subitem_relation_type_select":"NAID"}}]},"item_3_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00178280","subitem_source_identifier_type":"NCID"}]},"item_3_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0386443X","subitem_source_identifier_type":"ISSN"}]},"item_3_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"森下, 浩史"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"小林, 雅通"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"下村, 正樹"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"井口, 正俊"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"金子, 文俊"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"kyoikuS40_041.pdf","filesize":[{"value":"1.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"kyoikuS40_041.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/7572/files/kyoikuS40_041.pdf"},"version_id":"47e9b06c-015a-4789-8d15-f7bacb53a070"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"三方晶ポリオキシメチレン伸び切り鎖結晶の分光学的研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"三方晶ポリオキシメチレン伸び切り鎖結晶の分光学的研究"}]},"item_type_id":"3","owner":"2","path":["551"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-06-25"},"publish_date":"2013-06-25","publish_status":"0","recid":"7572","relation_version_is_last":true,"title":["三方晶ポリオキシメチレン伸び切り鎖結晶の分光学的研究"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T02:21:36.301911+00:00"}