{"created":"2023-05-15T16:35:53.630337+00:00","id":8910,"links":{},"metadata":{"_buckets":{"deposit":"13ac0c9b-5994-4253-8d8a-64b63d740668"},"_deposit":{"created_by":2,"id":"8910","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"8910"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00008910","sets":["14:21"]},"author_link":["35869","35872","35874","35868","35870","35871","35873"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-04-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"13","bibliographicPageEnd":"2788","bibliographicPageStart":"2782","bibliographicVolumeNumber":"69","bibliographic_titles":[{"bibliographic_title":"Tetrahedron"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Total synthesis of the pyrrolic marine natural products lukianols A (1) and B (2) has been achieved using N-benzenesulfonyl-3,4-dibromopyrrole (3) as a common starting material. The key synthetic strategy developed is the combined bromine-directed lithiation and palladium-catalyzed cross-coupling of 3 to produce 3,4-diarylpyrrol-2-carboxylates. Regioselective iodination of the phenolic intermediate 24 was thoroughly investigated for the synthesis of lukianol B.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Tetrahedron, 69(13), pp.2782-2788; 2013","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier Limited"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.tet.2013.01.077","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2013 Published by Elsevier Ltd."},{"subitem_rights":"NOTICE: this is the author’s version of a work that was accepted for publication in Tetrahedron. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Tetrahedron, 69, 13(2013)"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00404020","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Takamura, Kaoru"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsuo, Hisami"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Ayana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Junji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fukuda, Tsutomu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ishibashi, Fumito"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Iwao, Masatomo"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"Supplementary Data.pdf","filesize":[{"value":"2.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Supplementary Data.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/8910/files/Supplementary Data.pdf"},"version_id":"fd2c4caa-0445-419f-8326-9a1645f70f47"},{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-12-21"}],"displaytype":"detail","filename":"Tetra69_2782.pdf","filesize":[{"value":"653.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Tetra69_2782.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/8910/files/Tetra69_2782.pdf"},"version_id":"b031b394-3566-4008-bed3-8b2045875006"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Cross-coupling","subitem_subject_scheme":"Other"},{"subitem_subject":"Directed lithiation","subitem_subject_scheme":"Other"},{"subitem_subject":"Lukianols A, B","subitem_subject_scheme":"Other"},{"subitem_subject":"Pyrrole","subitem_subject_scheme":"Other"},{"subitem_subject":"Total synthesis","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Total synthesis of the marine natural products lukianols A and B","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Total synthesis of the marine natural products lukianols A and B"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-05-13"},"publish_date":"2013-05-13","publish_status":"0","recid":"8910","relation_version_is_last":true,"title":["Total synthesis of the marine natural products lukianols A and B"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-16T01:56:22.645259+00:00"}