{"created":"2023-05-15T16:29:59.373867+00:00","id":952,"links":{},"metadata":{"_buckets":{"deposit":"c8d70206-0b13-4d3e-94b1-d2702996d37e"},"_deposit":{"created_by":2,"id":"952","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"952"},"status":"published"},"_oai":{"id":"oai:nagasaki-u.repo.nii.ac.jp:00000952","sets":["14:21"]},"author_link":["4501","4500","4499","4503","4504","4502"],"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-05-27","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"25","bibliographicPageEnd":"8477","bibliographicPageStart":"8472","bibliographicVolumeNumber":"49","bibliographic_titles":[{"bibliographic_title":"Dalton Transactions"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Understanding of encapsulation processes in confined inner spaces of self-assembled hosts is important for the rational creation of supramolecular systems showing unusual reactivities and physical properties through molecular recognition. Herein we report the formation of luminescent supramolecular host-guest complexes consisting of a hydrogen-bonded resorcin[4]arene hexameric capsule and a variety of emissive Ir complex salts. The Ir complexes, accompanied by small counter anions (Cl-, Br-, NO2-, I- and NO3-), are trapped effectively to show large encapsulation-induced emission enhancement (EIEE) behavior, while Ir complexes having large counter anions (ClO4-, PF6- and OTf-) are not stabilized within the capsule, suggesting that the Ir complex cation is trapped together with its counter anion to form an ion-pair in the capsule. Hydrogen-bonding capabilities of the counter anions also contribute to stabilize host-guest association, because the counter anions trapped within the capsule were in contact with the hydrophilic surfaces of the capsule.","subitem_description_type":"Abstract"}]},"item_2_description_63":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Dalton transactions, 49(25), pp.8472-8477; 2020","subitem_description_type":"Other"}]},"item_2_publisher_33":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_2_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1039/D0DT01485K","subitem_relation_type_select":"DOI"}}]},"item_2_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"c The Royal Society of Chemistry 2020"}]},"item_2_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"14779226","subitem_source_identifier_type":"ISSN"}]},"item_2_source_id_8":{"attribute_name":"EISSN","attribute_value_mlt":[{"subitem_source_identifier":"14779234","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Horiuchi, Shinnosuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsuo, Chiharu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sakuda, Eri"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Arikawa, Yasuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Clever, Guido H."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Umakoshi, Keisuke"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-05-27"}],"displaytype":"detail","filename":"DT49_8472.pdf","filesize":[{"value":"655.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"DT49_8472.pdf","url":"https://nagasaki-u.repo.nii.ac.jp/record/952/files/DT49_8472.pdf"},"version_id":"11b3df0c-a4e1-42a0-85aa-23e01505b746"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Anion-mediated encapsulation-induced emission enhancement of an IrIII complex within a resorcin[4]arene hexameric capsule","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Anion-mediated encapsulation-induced emission enhancement of an IrIII complex within a resorcin[4]arene hexameric capsule"}]},"item_type_id":"2","owner":"2","path":["21"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-12-18"},"publish_date":"2020-12-18","publish_status":"0","recid":"952","relation_version_is_last":true,"title":["Anion-mediated encapsulation-induced emission enhancement of an IrIII complex within a resorcin[4]arene hexameric capsule"],"weko_creator_id":"2","weko_shared_id":2},"updated":"2023-05-15T23:00:29.052134+00:00"}