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一部にユニークな結晶構造を有するアルミニウムをはじめとする土類金属-EDTA 錯体(概論)
http://hdl.handle.net/10069/00041654
http://hdl.handle.net/10069/00041654e6d3f147-851f-40ed-a738-c9d3192b7495
名前 / ファイル | ライセンス | アクション |
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52_99_30.pdf (1.2 MB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2022-08-01 | |||||
タイトル | ||||||
タイトル | 一部にユニークな結晶構造を有するアルミニウムをはじめとする土類金属-EDTA 錯体(概論) | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Chelate | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Coordination chemistry | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Gallium | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Indium | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Polyaminocarboxylate | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Thallium | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者 |
野口, 大介
× 野口, 大介 |
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著者別名 | ||||||
姓名 | NOGUCHI, Daisuke | |||||
その他のタイトル | ||||||
その他のタイトル | EDTA complexes of aluminum and other earth metals with some unique crystal structures: A brief overview | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Aluminum, gallium, indium, and thallium, forming trivalent cations, are r eferred to as earth metals; only Tl also has stable monovalent one. The complexes of Al, for instance, have studied to elucidate industrial use and toxic effects in materials engineering and environmental science. Here, I briefly overview the reported crystal structures of earth metal-complexes chelated by EDTA (ethylenediaminetetraacetic acid) to deepen our knowledge and apply for further research. Bibliographic survey has revealed that 6 of Al-, 14 of Ga-, 6 of In-, and 2 of Tl(III)-EDTA were reported for the crystal structures, showing that the coordination numbers of Al3+ and Ga3+ are 6, In3+ and Tl3+ are 7 in the crystal state. The denticity of EDTA anions are not only hexadentate but also pentadentate (the fourth carboxy group is uncoordinated) in six complexes. A dinuclear Al2-EDTA complex, with two Al3+ bridged by (μ-OH-)2, has a unique cis-conformation of ethylenediamine moiety; it was appeared to have few other analogues. | |||||
書誌情報 |
長崎大学大学院工学研究科研究報告 en : Reports of Graduate School of Engineering, Nagasaki University 巻 52, 号 99, p. 30-37, 発行日 2022-07 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 18805574 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12601998 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 長崎大学大学院工学研究科 | |||||
出版者別言語 | ||||||
Graduate School of Engineering, Nagasaki University | ||||||
sortkey | ||||||
05 | ||||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 長崎大学大学院工学研究科研究報告, 52(99), pp.30-37; 2022 |