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後期第一系列遷移金属-EDTA キレートの比較構造解析
http://hdl.handle.net/10069/00042020
http://hdl.handle.net/10069/000420202499ea1e-d48a-4190-8804-61f56d47f102
名前 / ファイル | ライセンス | アクション |
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53_100_71.pdf (589.0 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2023-01-31 | |||||
タイトル | ||||||
タイトル | 後期第一系列遷移金属-EDTA キレートの比較構造解析 | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | D-block | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Denticity | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Sexidentate ligand | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Transition elements | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | X-ray crystallography | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者 |
野口, 大介
× 野口, 大介 |
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著者別名 | ||||||
姓名 | NOGUCHI, Daisuke | |||||
その他のタイトル | ||||||
その他のタイトル | Comparative structural analysis of late first-row transition metal-EDTA chelates | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Based on the data available in Cambridge Crystallographic Data Centre (CCDC), the crystal structures of late first-row transition metal-complexes chelated by ethylenediaminetetraacetic acid (EDTA) are overviewed. Herein, it is summarized that the crystal structures of 17 of FeIII-EDTA, 6 of FeII-EDTA, 21 of CoIII-EDTA, 14 of CoII-EDTA, 13 of Ni-EDTA, 22 of Cu-EDTA, and 7 of Zn-EDTA complexes (total 100 kinds) have coordination numbers (CN) ranging from 5 to 7, most have CN = 6(70/100), and the denticities of these chelates are tetra-, penta-, and hexadentate. In analytical chemistry, typically learned complexes of hexadentate and CN = 6 are found to be only 33 cases (ca. 33%), not major species in the late first-row transition metal-EDTA complexes, following up on the former review. | |||||
書誌情報 |
長崎大学大学院工学研究科研究報告 en : Reports of Graduate School of Engineering, Nagasaki University 巻 53, 号 100, p. 71-78, 発行日 2023-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 18805574 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12601998 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 長崎大学大学院工学研究科 | |||||
出版者別言語 | ||||||
Graduate School of Engineering, Nagasaki University | ||||||
sortkey | ||||||
10 | ||||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 長崎大学大学院工学研究科研究報告, 53(100), pp.71-78; 2023 |