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KI-Tetraethylene Glycol Complex as an Effective Catalyst for the Synthesis of Cyclic Thiocarbonates from Epoxides and CS2
http://hdl.handle.net/10069/38301
http://hdl.handle.net/10069/38301d65fe6d8-aaad-40a7-85f1-865aeedd01de
名前 / ファイル | ライセンス | アクション |
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EJOC2018_2022.pdf (740.8 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-05-09 | |||||
タイトル | ||||||
タイトル | KI-Tetraethylene Glycol Complex as an Effective Catalyst for the Synthesis of Cyclic Thiocarbonates from Epoxides and CS2 | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Alkali metals | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Carbonates | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Green chemistry | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Reaction mechanisms | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Sustainable chemistry | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Okada, Megumi
× Okada, Megumi× Nishiyori, Ryuichi× Kaneko, Shiho× Igawa, Kazunobu× Shirakawa, Seiji |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | An efficient synthesis of cyclic thiocarbonates from epoxides and CS2 under mild reaction conditions was achieved when a KI?tetraethylene glycol complex was used as a readily available and economic catalyst. The effects of various glycols and alkali metal halides were investigated in the present work to clarify the importance of both KI and tetraethylene glycol. The reaction mechanisms for the synthesis of cyclic thiocarbonates are discussed on the basis of the stereochemistry of the products. | |||||
書誌情報 |
European Journal of Organic Chemistry 巻 2018, 号 17, p. 2022-2027, 発行日 2018-05-08 |
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出版者 | ||||||
出版者 | Wiley-VCH Verlag GmbH & Co. KGaA | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1434193X | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1002/ejoc.201800284 | |||||
権利 | ||||||
権利情報 | c 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | |||||
権利 | ||||||
権利情報 | This is the accepted version of the following article: European Journal of Organic Chemistry, 2018(17), pp.2022-2027; 2018, which has been published in final form at http://dx.doi.org/10.1002/ejoc.201800284. | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | European Journal of Organic Chemistry, 2018(17), pp.2022-2027; 2018 |