WEKO3
アイテム
イオン交換紙による第四アンモニウム塩基および関連化合物の迅速な分離検出〔イオン交換ペーパークロマトグラフィーの裁判化学への応用-3-〕
http://hdl.handle.net/10069/33056
http://hdl.handle.net/10069/33056d0e72219-f310-4e01-b240-72471e49ff56
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
kyoikuS22_053.pdf (844.4 kB)
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| アイテムタイプ | 紀要論文 / Departmental Bulletin Paper(1) | |||||||
|---|---|---|---|---|---|---|---|---|
| 公開日 | 2013-08-01 | |||||||
| タイトル | ||||||||
| タイトル | イオン交換紙による第四アンモニウム塩基および関連化合物の迅速な分離検出〔イオン交換ペーパークロマトグラフィーの裁判化学への応用-3-〕 | |||||||
| 言語 | ||||||||
| 言語 | jpn | |||||||
| 資源タイプ | ||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||
| 資源タイプ | departmental bulletin paper | |||||||
| 著者 |
竹友, 一成
× 竹友, 一成
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| 著者別名 | ||||||||
| 識別子Scheme | WEKO | |||||||
| 識別子 | 26685 | |||||||
| 姓名 | Taketomo, Kazushige | |||||||
| その他のタイトル | ||||||||
| その他のタイトル | Rapid Separation and Identification of Quaternary Ammonium Bases and Related Compounds with Ion Exchange Paper | |||||||
| 抄録 | ||||||||
| 内容記述タイプ | Abstract | |||||||
| 内容記述 | In order to apply ion exchange paper chromatography to forensic chemistry, quaternary ammonium bases and related compounds, in the form of penodides, were examined whether they were chromatographically detected with the ion exchange paper. The ion exchange paper, amberlite SA-2 was used. A ethyl alcohol (or acetone) solution of the periodides was spotted at the starting point that was at a 4 cm distance from the bottom edge of the ion exchange paper strip. The strip was hung in a chamber at 30℃, the bottom edge of the strip was immersed in 1M Na2HPO4-NaOH buffer solution (pH 13.30), and the ascending development was applied. During the run, stainish brown colour of the periodide was faded away. After the run was completed, the strip was dried and passed through a freshly prepared solution of 2% phosphomolybdic acid in 1 N hydrochloric acid. The presence of quaternary ammonium bases and related compounds was evidenced by the appearance of the yellow spot. Under such a condition, Rf values of quaternary ammoniun bases and related compounds were as follows: 0.44 for choline chloride, 0.20 for neurine chloride, 0.18 for tetraethylammonium chloride, 0.00 for cetyltrimethylammonium bromide, 0.34 for caffeine, 0.11 (0.40) for antipyrine, 0.01 for ephedrine hydrochloride, and 0.74 for creatinine. It was impossible to detect betaine and atropine sulfate by the above method. It is presumed that the fading of the stainish brown periodide, during the run, may be mainly due to the following mechanism: (organic base) Ix + x NaOH→organic base + x/2 NaI + x/2 NaIO + x/2 H2O Besides, this method was applied to the detection of choline in human urine, human semen, human internal organs, and rabbit internal organs. | |||||||
| 書誌情報 |
長崎大学教育学部自然科学研究報告 en : Science bulletin of the Faculty of Education, Nagasaki University 巻 22, p. 53-63, 発行日 1971-02-28 |
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| ISSN | ||||||||
| 収録物識別子タイプ | ISSN | |||||||
| 収録物識別子 | 0386443X | |||||||
| 書誌レコードID | ||||||||
| 収録物識別子タイプ | NCID | |||||||
| 収録物識別子 | AN00178280 | |||||||
| 著者版フラグ | ||||||||
| 出版タイプ | VoR | |||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||
| 論文ID（NAID） | ||||||||
| 関連タイプ | isIdenticalTo | |||||||
| 識別子タイプ | NAID | |||||||
| 関連識別子 | 40018180763 | |||||||
| 出版者 | ||||||||
| 出版者 | 長崎大学教育学部 | |||||||
| 引用 | ||||||||
| 内容記述タイプ | Other | |||||||
| 内容記述 | 長崎大学教育学部自然科学研究報告. vol.22, p.53-63; 1971 | |||||||
