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Efficient and environmental-friendly dehydration of fructose to 5-hydroxymethyl-2-furfural in water under high pressure of CO2
http://hdl.handle.net/10069/37345
http://hdl.handle.net/10069/3734554ef487f-92e7-4e7d-af10-10561dbe003c
名前 / ファイル | ライセンス | アクション |
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TetLet57_4742.pdf (263.6 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-10-20 | |||||
タイトル | ||||||
タイトル | Efficient and environmental-friendly dehydration of fructose to 5-hydroxymethyl-2-furfural in water under high pressure of CO2 | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Biomass | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Carbonic acid | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | CO2 | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Dehydration reaction | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Fructose | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Motokucho, Suguru
× Motokucho, Suguru× Morikawa, Hiroshi× Nakatani, Hisayuki× Noordover, Bart A.J. |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | To develop reaction systems of chemical conversion of biomass, fructose was heated in an aqueous medium under pressurized CO2, which caused in situ generation of carbonic acid. It gave 5-hydroxymethyl-2-furfural (HMF) as a dehydration product in good yields. The maximum yield of HMF was 92% in the reaction at 90 °C under 7.0 MPa of CO2 for 168 h. The reaction proceeded in the absence of any other reagents such as non-volatile acids, organic solvents, inorganic, and organic salts. It means green, environmental-friendly, and efficient process was achieved for production of HMF. | |||||
書誌情報 |
Tetrahedron Letters 巻 57, 号 42, p. 4742-4745, 発行日 2016-10-19 |
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出版者 | ||||||
出版者 | Elsevier Ltd. | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00404039 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.tetlet.2016.09.036 | |||||
権利 | ||||||
権利情報 | c 2016 Elsevier Ltd. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Tetrahedron Letters, 57(42), pp.4742-4745; 2016 |