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Formation of novel ene-yne substituted β-diketonato ruthenium(III) complexes by the Heck-like reactions on coordinated ligand
http://hdl.handle.net/10069/25253
http://hdl.handle.net/10069/25253f9e0c6f1-f7c4-474b-b3a3-8126b805cb99
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
ICA374_654.pdf (192.1 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2011-06-20 | |||||
| タイトル | ||||||
| タイトル | Formation of novel ene-yne substituted β-diketonato ruthenium(III) complexes by the Heck-like reactions on coordinated ligand | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | β-Diketone complex | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | 1H NMR spectroscopy | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Acetylenic compounds | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | DFT calculations | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Ruthenium(III) complex | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | X-ray crystal | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Hoshino, Yoshimasa
× Hoshino, Yoshimasa× Ozaki, Fumika× Igarashi, Satoshi× Yukawa, Yasuhiko |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Two new ene-yne substituted 2,4-pentanedionatoruthenium(III) complexes formed by the Heck-like reactions in the course of the Sonogashira reactions. The two complexes are structural isomers; one is [Ru(E-1,4-mBSima)(dpm)2] and another is [Ru(E-2,4-mBSima)(dpm)2], where E-1,4-mBSima is E-3-(1,4-bis(trimethylsilyl)-1-butene-3-ynyl)-2,4-pentanedionate, E-2,4-mBSima is E-3-(2,4-bis(trimethylsilyl)-1-butene-3-ynyl)-2,4-pentanedionate, and dpm is dipivaloylmethanate (2,2,6,6-tetramethylheptan-3,5-dionate). Both of complexes have been characterized by 1H NMR and infrared spectroscopies, mass spectrometry, and electrochemistry. [Ru(E-1,4-mBSima)(dpm)2] has also been characterized by X-ray crystallography. The ruthenium(III) is coordinated in an octahedral arrangement by the oxygen atoms of three β-diketonate ligands. The dihedral angle between the 2,4-pentanedionato chelate ring and the ene-yne plane on the E-1,4-mBSima ligand is 91°. The ene-yne group in [Ru(E-1,4-mBSima)(dpm)2] is fixed either in the solution state suggested by the 1H NMR spectrum with no symmetry. | |||||
| 書誌情報 |
Inorganica Chimica Acta 巻 374, 号 1, p. 654-659, 発行日 2011-08-01 |
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| 出版者 | ||||||
| 出版者 | Elsevier BV | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 00201693 | |||||
| EISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 18733255 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA10761133 | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1016/j.ica.2011.03.026 | |||||
| 権利 | ||||||
| 権利情報 | © 2011 Elsevier B.V. All rights reserved. | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| 引用 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Inorganica Chimica Acta, 374(1), pp.654-659; 2011 | |||||
