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希土類-エチレンジアミン四酢酸(REE-EDTA)の結晶状態における配位数:ミニ・レビュー
http://hdl.handle.net/10069/0002000111
http://hdl.handle.net/10069/00020001118ebdc2ee-df0a-4b83-860e-28ba8c2ebf2d
名前 / ファイル | ライセンス | アクション |
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53_101_46.pdf (638 KB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||||
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公開日 | 2023-08-03 | |||||||
タイトル | ||||||||
言語 | ja | |||||||
タイトル | 希土類-エチレンジアミン四酢酸(REE-EDTA)の結晶状態における配位数:ミニ・レビュー | |||||||
言語 | ||||||||
言語 | jpn | |||||||
キーワード | ||||||||
言語 | en | |||||||
主題Scheme | Other | |||||||
主題 | Aminopolycarboxylate | |||||||
キーワード | ||||||||
言語 | en | |||||||
主題Scheme | Other | |||||||
主題 | Chelate | |||||||
キーワード | ||||||||
言語 | en | |||||||
主題Scheme | Other | |||||||
主題 | Complex ion | |||||||
キーワード | ||||||||
言語 | en | |||||||
主題Scheme | Other | |||||||
主題 | Lanthanide | |||||||
資源タイプ | ||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||
資源タイプ | departmental bulletin paper | |||||||
著者 |
野口, 大介
× 野口, 大介
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著者別名 | ||||||||
姓名 | NOGUCHI, Daisuke | |||||||
言語 | en | |||||||
その他のタイトル | ||||||||
その他のタイトル | Coordination numbers for rare-earths ethylenediaminetetraacetate (REE-EDTA) in crystalline state: a mini-review | |||||||
言語 | en | |||||||
抄録 | ||||||||
内容記述タイプ | Abstract | |||||||
内容記述 | The crystal structures of rare earth elements ethylenediaminetetraacetate (REE-EDTA), including potential applications towards biomedical engineering in MRI, have been briefly reviewed by some researchers. However, there is no systematization of almost all of REE-EDTA complexes; therefore, in the present study, a total of 114 kinds of REE-EDTA (except Sc, Pm, and Tm) were searched in the Cambridge Crystallographic Data Centre (CCDC) and their coordination numbers (C.N.) are summarized. The largest number of registered REE-EDTA is La-EDTA for 22 kinds, followed by 15 Gd-EDTA. The C.N. of each complex ranged from 10 to 9 for light REE (La–Sm) and 10 to 8 for heavy REE (Y and Eu–Lu), suggesting that a decreasing in the C.N. of lanthanoid (Ln)-EDTA is considered to be due to ‘lanthanoid contraction’. The C.N. of Tb-EDTA deviated slightly from the overall decreasing C.N. in Ln-EDTA complexes would be because of a lack of a sufficient number of the studied samples. | |||||||
言語 | en | |||||||
書誌情報 |
ja : 長崎大学大学院工学研究科研究報告 en : Reports of Graduate School of Engineering, Nagasaki University 巻 53, 号 101, p. 46-53, 発行日 2023-07 |
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ISSN | ||||||||
収録物識別子タイプ | ISSN | |||||||
収録物識別子 | 18805574 | |||||||
書誌レコードID | ||||||||
収録物識別子タイプ | NCID | |||||||
収録物識別子 | AA12601998 | |||||||
著者版フラグ | ||||||||
出版タイプ | VoR | |||||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||
出版者 | ||||||||
言語 | ja | |||||||
出版者 | 長崎大学大学院工学研究科研究報告 | |||||||
出版者別言語 | ||||||||
en | ||||||||
Reports of Graduate School of Engineering, Nagasaki University | ||||||||
sortkey | ||||||||
07 | ||||||||
引用 | ||||||||
内容記述タイプ | Other | |||||||
内容記述 | 長崎大学大学院工学研究科研究報告, 53(101), pp.46-53; 2023 | |||||||
言語 | ja |