{"_buckets": {"deposit": "46693d09-7b4f-4230-a629-d96041c0acb8"}, "_deposit": {"created_by": 6, "id": "2000815", "owner": "6", "owners": [6], "pid": {"revision_id": 0, "type": "depid", "value": "2000815"}, "status": "published"}, "_oai": {"id": "oai:nagasaki-u.repo.nii.ac.jp:02000815", "sets": ["11"]}, "author_link": [], "item_2_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2024-04-19", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "8", "bibliographicPageStart": "art. no. 1874", "bibliographicVolumeNumber": "29", "bibliographic_titles": [{"bibliographic_title": "Molecules", "bibliographic_titleLang": "en"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "An oxidative C–C bond cleavage of tert-cycloalkanols with tetramethylammonium hypochlorite (TMAOCl) has been developed. TMAOCl is easy to prepare from tetramethylammonium hydroxide, and the combination of TMAOCl and AcOH effectively promoted the C–C bond cleavage in a two-phase system without additional phase-transfer reagents. Unstrained tert-cycloalkanols were transformed into ω-chloroalkyl aryl ketones in moderate to excellent yields under metal-free and mild reaction conditions.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_2_description_63": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "Molecules, 29(8), art. no. 1874; 2024", "subitem_description_language": "en", "subitem_description_type": "Other"}]}, "item_2_publisher_33": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "MDPI", "subitem_publisher_language": "en"}]}, "item_2_relation_12": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.3390/molecules29081874", "subitem_relation_type_select": "DOI"}}]}, "item_2_rights_13": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© 2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).", "subitem_rights_language": "en"}]}, "item_2_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1420-3049", "subitem_source_identifier_type": "EISSN"}]}, "item_2_version_type_16": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hanazawa, Natsumi", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Kuriyama, Masami", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Yamamoto, Kosuke", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Onomura, Osamu", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_access", "date": [{"dateType": "Available", "dateValue": "2024-05-07"}], "download_preview_message": "", "file_order": 0, "filename": "M29_1874.pdf", "filesize": [{"value": "1.5 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "application/pdf", "size": 1500000.0, "url": {"url": "https://nagasaki-u.repo.nii.ac.jp/record/2000815/files/M29_1874.pdf"}, "version_id": "011fe765-6c5b-4305-81cb-b6df7a9a10d4"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "C–C bond cleavage", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "oxidation", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "tert-cycloalkanols", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "tetramethylammonium hypochlorite", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ω-chloroalkyl aryl ketones", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of ω-Chloroalkyl Aryl Ketones via C–C Bond Cleavage of tert-Cycloalkanols with Tetramethylammonium Hypochlorite", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Synthesis of ω-Chloroalkyl Aryl Ketones via C–C Bond Cleavage of tert-Cycloalkanols with Tetramethylammonium Hypochlorite", "subitem_title_language": "en"}]}, "item_type_id": "2", "owner": "6", "path": ["11"], "permalink_uri": "http://hdl.handle.net/10069/0002000815", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2024-05-07"}, "publish_date": "2024-05-07", "publish_status": "0", "recid": "2000815", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of ω-Chloroalkyl Aryl Ketones via C–C Bond Cleavage of tert-Cycloalkanols with Tetramethylammonium Hypochlorite"], "weko_shared_id": -1}
Synthesis of ω-Chloroalkyl Aryl Ketones via C–C Bond Cleavage of tert-Cycloalkanols with Tetramethylammonium Hypochlorite
http://hdl.handle.net/10069/0002000815
http://hdl.handle.net/10069/0002000815