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三方晶ポリオキシメチレン伸び切り鎖結晶の分光学的研究
http://hdl.handle.net/10069/32446
http://hdl.handle.net/10069/32446fe2510e4-80d7-44a3-aa8c-9f8b5cb3daac
名前 / ファイル | ライセンス | アクション |
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kyoikuS40_041.pdf (1.9 MB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2013-06-25 | |||||
タイトル | ||||||
タイトル | 三方晶ポリオキシメチレン伸び切り鎖結晶の分光学的研究 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者 |
森下, 浩史
× 森下, 浩史× 小林, 雅通× 下村, 正樹× 井口, 正俊× 金子, 文俊 |
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著者別名 | ||||||
姓名 | Morishita, Hirofumi | |||||
著者別名 | ||||||
姓名 | Kobayashi, Masamichi | |||||
著者別名 | ||||||
姓名 | Shimomura, Masaki | |||||
著者別名 | ||||||
姓名 | Iguchi, Masatoshi | |||||
著者別名 | ||||||
姓名 | Kaneko, Fumitoshi | |||||
その他のタイトル | ||||||
その他のタイトル | Vibrational Spectroscopic Study on Trigonal Polyoxymethylene consisting of the Extended Molecular Chains | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Polarized raman spectra of needle-like and feather-shaped single crystals of trigonal polyoxymethylene (t-POM) consisting of fully extended molecular chains, were measured on a micron-sized cystal by means of the Raman microprobe technique. It was clear that the spectra of these single crystals were quite similar to the spectra of the moth-shaped t-POM single crystals which were obtained by the thermal-induced phase transition of the moth-shaped single crystals of orthorhombic polyoxymethylene1). Polarized Raman spectra of pressurized superdrawn fibers, which were well-oriented and semitransparent samples of t-POM, were obtained theoretically by the ordinary right-angle scattering at room temperature2). In the present study, we could observe the spectraof [YY] polarization of the superdrawn fibers. In addition, twobandsat 1230 and 462 cm-1 in the [YX] polarization, and one band at 198 cm-1 in the[YZ], were newly detected by polarized Raman measurements without the filter for the exitation laser beam, respectivley. And polarized infrared spectra of these fibers were measured, too. The bond assignments of t-POM including the C-H streching vibration reagion were able to be confirmed on the basis of these polarized spectral data. The angular dispersion of E1(7) and E1(8) were measured and discussed on the LO-TO splitting. Raman spectra of needle-like single crystals of polyoxymethylene-d2 consisting of fully extended molecular chains were measured, and it was discussed on the E2 modes. | |||||
書誌情報 |
長崎大学教育学部自然科学研究報告 en : Science bulletin of the Faculty of Education, Nagasaki University 巻 40, p. 41-54, 発行日 1989-02-28 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0386443X | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00178280 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
論文ID(NAID) | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | NAID | |||||
関連識別子 | 40002768785 | |||||
出版者 | ||||||
出版者 | 長崎大学教育学部 | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 長崎大学教育学部自然科学研究報告. vol.40, p.41-54; 1989 |