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Diastereoselective arylation of l-proline derivatives at the 5-position
http://hdl.handle.net/10069/18699
http://hdl.handle.net/10069/186995b98f2c1-33a3-40cc-8465-5b6b5a63b5c5
名前 / ファイル | ライセンス | アクション |
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Tetra64_7498.pdf (177.6 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-07-08 | |||||
タイトル | ||||||
タイトル | Diastereoselective arylation of l-proline derivatives at the 5-position | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Diastereoselective | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Organocatalysis | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Asymmetric reduction of imines | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | C2-Symmetrical pyrrolidine | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Proline derivative | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Onomura, Osamu
× Onomura, Osamu× Kirira, Peter G× Tanaka, Toshimitsu× Tsukada, Shinsuke× Matsumura, Yoshihiro× Demizu, Yosuke |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Diastereoselective introduction of nucleophiles into L-proline derivatives at the 5-position was achieved with suitable selection of N-protecting group. N-Methoxycarbonylated or benzyloxycarbonylated L-proline derivatives reacted with arene to give cis-arylated products. On the other hand, N-benzoylated L-proline derivative preferentially gave trans-arylated product which could be easily transformed into optically active C2-symmetrical pyrrolidine derivative. Such derivative 5, worked well as an organic activator in the asymmetric reduction of aromatic imines by Cl3SiH. | |||||
書誌情報 |
Tetrahedron 巻 64, 号 32, p. 7498-7503, 発行日 2008-08-04 |
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出版者 | ||||||
出版者 | Elsevier BV | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00404020 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00861787 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.tet.2008.06.004 | |||||
権利 | ||||||
権利情報 | Copyright (c) 2008 Elsevier Ltd All rights reserved. | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Tetrahedron, 64(32), pp.7498-7503; 2008 |