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光学活性基をもつフラビン類の合成とその不二水素移動反応
http://hdl.handle.net/10069/24193
http://hdl.handle.net/10069/2419314671990-0112-42f9-9b2a-af118be67af3
名前 / ファイル | ライセンス | アクション |
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kogaku15_25_09.pdf (408.6 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2010-10-13 | |||||
タイトル | ||||||
タイトル | 光学活性基をもつフラビン類の合成とその不二水素移動反応 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者 |
中尾, 英樹
× 中尾, 英樹× 新海, 征治× 真鍋, 修 |
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著者別名 | ||||||
姓名 | Nakao, Hideki | |||||
著者別名 | ||||||
姓名 | Shinkai, Seiji | |||||
著者別名 | ||||||
姓名 | Manabe, Osamu | |||||
その他のタイトル | ||||||
その他のタイトル | Synthesis and Asymmetrie Hydrogen Transfer Reactions of Optically Active Flavins | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Flavins bearing an optically active substituent at N(10) (1-α and 1-b) were synthesized. As the substituent is sterically bulky, the rate constants for the oxidation of NADH model compounds which possibly proceeds via a face-to-face orientation were somewhat smaller than those of conventional flavins. We have found that the oxidation of optically active NADH model compounds by 1-b and tetra-O-acetylriboflavin occurs in an asymmetric manner. This is the first example for the in vitro asymmetric hydrogen transfer from NADH models to flavins. | |||||
書誌情報 |
長崎大学工学部研究報告 en : Reports of the Faculty of Engineering, Nagasaki University 巻 15, 号 25, p. 67-72, 発行日 1985-07 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 02860902 | |||||
EISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 18805574 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00178418 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | 長崎大学工学部 | |||||
出版者別言語 | ||||||
Faculty of Engineering, Nagasaki University | ||||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 長崎大学工学部研究報告, 15(25), pp.67-72; 1985 |