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Methylation of a nitrosylruthenium complex bearing a hydridotris(pyrazolyl)borate ligand
http://hdl.handle.net/10069/34602
http://hdl.handle.net/10069/3460224e07e07-e177-496d-a8c7-80a326470ef2
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
JOC755_12.pdf (708.5 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2014-07-31 | |||||
| タイトル | ||||||
| タイトル | Methylation of a nitrosylruthenium complex bearing a hydridotris(pyrazolyl)borate ligand | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Alkylation | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Hydridotris(pyrazolyl)borate | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Nitrogen monoxide | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Nitrosylruthenium | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Protonolysis | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Arikawa, Yasuhiro
× Arikawa, Yasuhiro× Yamaguchi, Soseki× Haige, Ryohei× Oshiro, Eriko× Umakoshi, Keisuke× Onishi, Masayoshi |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Reaction of [TpRuCl2(NO)] (1) (Tp = HB(pyrazol-1-yl) 3) with dimethylzinc, Zn(Me)2, gave rise to a dimethyl complex [TpRu(Me)2(NO)] (2) and a monomethyl complex [TpRuCl(Me)(NO)] (3) in good yields, while the use of a Grignard reagent, MeMgCl, as the alkylating agents led to isolation of 2 in low yield. Complexes 2 and 3 were confirmed by single-crystal X-ray diffraction analyses. Treatment of 2 with triflic acid, CF3SO3H, afforded a triflato complex [TpRu(Me){OS(O)2CF3}(NO)] (4). | |||||
| 書誌情報 |
Journal of Organometallic Chemistry 巻 755, p. 12-15, 発行日 2014-04-01 |
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| 出版者 | ||||||
| 出版者 | Elsevier | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0022328X | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1016/j.jorganchem.2013.12.054 | |||||
| 権利 | ||||||
| 権利情報 | c 2014 Elsevier B.V. All rights reserved. | |||||
| 権利 | ||||||
| 権利情報 | NOTICE: this is the author’s version of a work that was accepted for publication in Journal of Organometallic Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Organometallic Chemistry, 755, (2014) | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| 引用 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Journal of Organometallic Chemistry, 755, pp.12-15; 2014 | |||||
