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Facile synthesis of both enantiomers of (pyrrolidin-2-yl)phosphonate from l-proline
http://hdl.handle.net/10069/26344
http://hdl.handle.net/10069/26344254144e1-b096-4ef3-b1ce-60b16646c980
名前 / ファイル | ライセンス | アクション |
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Tetra67_9411.pdf (220.0 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2011-11-11 | |||||
タイトル | ||||||
タイトル | Facile synthesis of both enantiomers of (pyrrolidin-2-yl)phosphonate from l-proline | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | (Pyrrolidin-2-yl)phosphonate | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Arbusov reaction | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Diastereoselective phosphorylation | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | l-Proline | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Hirata, Shigeo
× Hirata, Shigeo× Kuriyama, Masami× Onomura, Osamu |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Diastereoselective introduction of phosphono groups into l-proline derivatives at the 5-position was achieved with suitable selection of N-protecting group. N-Benzoyl-l-prolinate preferentially gave trans-phosphorylated products, which could be easily transformed into (S)-(pyrrolidin-2-yl)phosphonates. On the other hand, N-benzyloxycarbonyl-l-prolinate reacted with phosphite to give cis-substituted products, which could be easily transformed into (R)-(pyrrolidin-2-yl)phosphonates. | |||||
書誌情報 |
Tetrahedron 巻 67, 号 48, p. 9411-9416, 発行日 2011-12 |
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出版者 | ||||||
出版者 | Elsevier BV | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00404020 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00861787 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.tet.2011.09.080 | |||||
権利 | ||||||
権利情報 | Copyright © 2011 Elsevier Ltd. All rights reserved. | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Tetrahedron, 67(48), pp.9411-6416; 2011 |